Efficiently Producing Fuels from Waste CO2 and Off-peak Wind or Other Renewable Energy


Updated 12/13/2010

Shale Oil

There have been numerous starry-eyed projections of the cost of producing shale oil over the last four decades. Many have said it can be produced at $18-$40/bbl, but these projections ignored the realities of rapidly increasing costs of materials, labor, and energy, as we will show in the following brief summary of our analysis. Our estimates in 2007 were in the range of $110-150/bbl. As of late 2010, we think these estimates are still accurate.

Oil shale production peaked globally in 1980 at about 46 Mt/yr, with an energy content equivalent to ~0.02% of current global energy usage. Oil shale production has been steadily declining since then, and today is about half that amount. Undoubtedly, oil shale and shale oil production will begin growing again, as oil seems likely to average $120/bbl in 2012, at which point shale oil could begin to look attractive. However, it will not grow quickly because the capital investment required will be enormous and there will be strong resistance on the basis of environmental concerns, whether real or perceived. Investors will choose to put their money into lower cost and cleaner options, such as Windfuels.

A recent small demonstration of the Shell In-situ Conversion Process (ICP) showed that after several years of in-situ central heating with peripheral wall freezing, a small array of holes about 500 m deep (in a choice location) can produce ~10,000 bbl of light, sweet crude before running dry. A lot of processes have been tried for getting oil from oil shale, but only ICP appears likely to satisfy both environmental and economic concerns. However, it has economic limitations. First of all, because of both drilling costs and heat leaks, ICP is practical only in the thickest and richest formations – those containing over 20 gal/ton, over 30 m thick, and extending over areas of at least tens of acres. There is an enormous amount of oil shale in deposits less than 10 m thick, and there is an enormous amount containing under 15 gal/ton. However, the total US resources that meet all three requirements for ICP is a small fraction of the total 2 trillion barrels often cited. A resource 50 m thick containing 30 gal/ton is equivalent to 400,000 BOE (barrels of oil equivalent) per acre.

The economics of shale oil are firstly limited by the time constant for thermal diffusion from the heater wells. (This time constant is proportional to the product of the logarithm and the square of the distance from the well). Heater and producer wells will be required on a grid spacing of about 10 to 12 m if oil production is desired in a reasonable period of time – two to four years of pre-heating, followed by a year or two of good production. The 30-m minimum deposit thickness is needed for acceptable vertical heat losses over the development period.

The drilling costs for fairly shallow heater and producer wells (300 to 600 m) are about $500K per grid surface unit – that is, a 100 to 150 m2 surface square containing one heater well and one producer well. The heating energy required for a deposit 100 m thick for a grid spacing of 10 m is about 13,000 GJ per heater well, over two-thirds of which is needed in the first two years of preheating. The only practical final-heating option is electrical, as the heating must be applied with a complex dependence on both depth and time that is responsive to the local conditions. Some of the initial heating could be done with a cheaper source.

The current mean cost of industrial electrical power is $18/GJ, but the cost from clean coal with 90% of its CO2 sequestered will probably be $28/GJ by 2015. Hence, the total heating cost (mostly during the first two years) will be $360K per heater (again, for a deposit 100 m thick, with a 10 m grid). Oil production would begin two years after initial heating, rise for a year or two, and then quickly decline. The total yield may be 12,000 bbl per heater well. The above up-front costs just for drilling and preheating are over $60 per barrel of crude, and these estimates really appear optimistic from more recent trends in well drilling costs. They come straight from the physics, mature drilling technologies, and realistic clean electrical energy prices less than a decade from now. Another $10/bbl will be needed for heating and freezing over the remaining life of the well.

It might be argued that the above drilling costs will come down with scale-up and a slightly coarser grid (12 m). However, material costs have skyrocketed over the past decade. Moreover, the drill casings must withstand much higher temperatures than normal wells and be of rather large diameter (at least 30 cm) for adequate heat or vapor transfer. The heating energy per barrel of product is independent of the grid spacing and usually will be higher than calculated above, as generally (after a few extremely choice sites are claimed) there will be layers of non-producing rock between layers of oil shale.

There are a number of additional components to the costs, but they are more difficult to estimate precisely. The down-well costs at 800 K for the sensors and the electrical insulation (that still must provide the high heat transfer to the well casing) will be substantial. A realistic estimate is that these costs might be half of the heater-well drilling costs – about $150K per unit, or ~$12/bbl. The outer perimeter freeze-wall costs (wells, refrigerators, and power) will add another $10/bbl, and a similar amount will be needed to cover site reclamation. The crude oil produced from the pyrolyzed oil shale is high in nitrogen compounds (much higher than heavy oils), which are more costly to remove than sulfur, though otherwise the oil is of very high grade. Thus, a reasonable estimate is that petroleum (not including a carbon tax) will need to average over $110/bbl for prime oil-shale deposits to be competitive – not the $18 to $75/bbl claimed by proponents. The carbon tax recently recommended by the IEA will eventually add about $30/bbl to the cost of petroleum and at least that to low-carbon shale oil.

The energy from the final fuel products (about 10,000 bbl) will be about 60,000 GJ per heater well, or about 5 times the electrical heating required. However, the input energy in a clean-coal power plant is three times its output, and there are substantial additional energy inputs to the ICP process – especially, the drilling and the freeze wall. The net result is that energy in the liquid fuel produced is not much more than the total coal input energy if the CO2 from the power plant is sequestered.

As each pair of wells (heater and producer) produces only 10,000 bbl of fuel over their lifetime (for a deposit 100 m thick), tens of millions of wells will need to be drilled over the coming decades if shale oil is to make a significant contribution to our energy needs. For comparison, a convention oil well will produce 3 to 50 times as much oil in one day as a shale-oil well produces over its entire lifetime.

The 160-acre site Shell plans to use for its first demonstration (The Mahogany research Project, in northwestern Colorado) is indeed exceptional. It contains 2 million bbls per acre in a formation that averages over 300 m thick at about 26 gal/ton with very thin non-producing interleaved zones. It also has excellent natural seals above and below. The heating requirement per barrel for this site may be 10% less than the above estimate for the more typical (but still prime) 100-m-thick deposit, and Shell’s energy cost will be much less, as there are no plans for CO2 sequestration.

In summary, “low-carbon” shale oil (carbon intensity similar to conventional oil) from prime deposits 100-m thick should compete when oil averages over $110/bbl, but there are still concerns about ground water contamination after the freeze walls are abandoned. High-quality deposits 30-m thick should compete in a carbon-constrained world when oil averages over $130/bbl. However, the scale-up of shale-oil will be slow for a combination of reasons: (1) it developed a very dirty reputation over the last three decades, (2) the demonstrations for at least the next six years are likely to have carbon intensity 80% greater than that of petroleum, and (3) it is not clear if Shell plans to license its ICP patents to competitors.

Hence, shale-oil is unlikely to contribute more than 0.5% to global oil production by 2020 and thus will have negligible effect on the price of oil by then. Even the most “environmentally sensitive” ICP shale oil (powered by clean-coal plants, with 90% CO2 sequestration) will still be 15% more carbon intensive than conventional petroleum, and both will probably be taxed at $30/bbl by 2018. Moreover, peak coal may be only 25 years away, so there really isn’t any spare coal for use in pyrolyzing the oil shale.

1. Adam Brandt, “Converting Green River oil shale to liquid fuels with ATP and ICP technologies: energy efficiency and GHG emissions”, Univ. CA, Berkeley, 2007, http://abrandt.berkeley.edu/shale/Brandt_Converting_Green_River_oil_shale_to_liquid_fuels.pdf

2. http://en.wikipedia.org/wiki/Oil_shale

 

 
The amount of oil in shale sites suitable for economic recovery is a very small fraction of the 2 trillion barrels often cited.
 
A conventional oil well produces 3 to 50 times as much oil in one day as a shale-oil well produces over its entire 8 year lifetime.
 
By the methods currently in progress, the carbon emissions from shale oil will be over 70% greater than those of conventional oil.
 
“Low-carbon” shale-oil is still just as bad for the climate as conventional oil.
 
The energy in the liquid fuels produced by the low-carbon ICP process in most shale formations will actually be less than that in the coal consumed by the power plants to pyrolyze the oil shale.

In the prime shale-oil sites, the liquid fuel energy may be only 50% more than that of the coal also consumed.

 
Low-carbon shale-oil is not likely to be produced before 2018, and it will probably cost over $130/bbl from most sites.
 
Shale-oil is not likely to contribute more than 0.5% to total oil supply by 2020.
 
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